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Title: ?ON THE ELECTRODEPOSITION OF 80MBR,8°BRAND 82BRSPECIES FROM (11,1)ACTI- VATED DIBROMOMETHANE -N,N-DIMETHYLANILINE MIXTURE
Authors: M.R. ZAMAN
Journal: Pakistan Journal of Scientific and Industrial Research (Series B: Biological Sciences)
Publisher: PCSIR Scientific Information Centre
Country: Pakistan
Year: 1997
Volume: 40
Issue: 1-4
Language: English
Keywords: Nuc\eogenic bromine speciesElectrodepositionAmine scavenger.
In a recent study [11, it was observed that aniline failed to exert its scavenging action in dibromomethane-aniline or dibromoethane-aniline mixtures due to the formation of crys- tals in the systems and the activities of electrodeposited radiobromines fell off sharply. The experiment with dibromomethane (DBM) in N,N-dimethylaniline (N,N- DMA) showed the same decreasing trend regarding the.elec- trode activities. Here, we present the results of our study on energetic bromine reactions in DBM -N,N-DMA mixtures by charge plate collection experiments and discuss the mecha- nism of stabilisation mode of sOmBr,sOBrand 82Brspecies in the system.
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