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?CHEMICAL KINETIC MODELLING STUDIES Part-I. The Reaction of Hydrogen Chloride with DI-Tertiary Butyl Peroxide

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Title: ?CHEMICAL KINETIC MODELLING STUDIES Part-I. The Reaction of Hydrogen Chloride with DI-Tertiary Butyl Peroxide

Authors: M. ANWAR KHAN, L. BATT

Journal: Pakistan Journal of Scientific and Industrial Research (Series B: Biological Sciences)

HEC Recognition History
Category From To
Y 2023-07-01 2024-09-30
Y 2022-07-01 2023-06-30
Y 2021-07-01 2022-06-30
Y 2020-07-01 2021-06-30
Y 1900-01-01 2005-06-30

Publisher: PCSIR Scientific Information Centre

Country: Pakistan

Year: 1996

Volume: 39

Issue: 1-4

Language: English

Keywords: KineticElementary ratesModelling studies.

Categories
Physical Chemistry (230) Chemical Kinetics (30) Chemistry (7379) Chemical Engineering (4680) Materials Science (8025)

Abstract

The chemical kinetic modelling studies of the reaction of three torr of hydrogen chloride and one torr of di-t- butyl peroxide (dtBP) mixture was carried out, at 383°K, over a reaction time of 0-2500 seconds. The "Gear" programme was used to model this study. This modelling system assisted in choosing the reaction steps for a probable mecha- nism and in the assessment of rate parameters for individual steps in reaction mechanism.

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