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Title: Synthesis of amide-based surfactants from fatty acid methyl ester: Effect of solvent ratio and stirring speed
Authors: Zuhrina Masyithah, Samuel Oktavianus Purba, Dinar Rajagukguk
Journal: ARPN Journal of Engineering and Applied Sciences
Publisher: Khyber Medical College, Peshawar
Country: Pakistan
Year: 2020
Volume: 15
Issue: 4
Language: English
The synthesis of surfactant fatty alkanolamide i.e. coco mono-ethanolamide was observed in this study. The fatty acid methyl ester (FAME) resulted from trans-esterification of coconut oil, treated with mono-ethanolamine to be coco mono-ethanolamide, using ZrCl4 as a catalyst and tert-amyl alcohol as a solvent. The observed reaction variables are the solvent ratio and stirring speed, and their effect on the converted FAME. The results showed that the 4:1 (v/w FAME) solvent ratio, and 300 rpm stirring speed gave the best results. Structural tests performed with FT-IR spectroscopy show that the surfactant obtained includes the fatty alkanolamide group. The results of this study are expected to produce cheap fatty alkanolamide surfactants obtained from renewable raw materials.
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