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Synthesis of amide-based surfactants from fatty acid methyl ester: Effect of solvent ratio and stirring speed


Article Information

Title: Synthesis of amide-based surfactants from fatty acid methyl ester: Effect of solvent ratio and stirring speed

Authors: Zuhrina Masyithah, Samuel Oktavianus Purba, Dinar Rajagukguk

Journal: ARPN Journal of Engineering and Applied Sciences

HEC Recognition History
Category From To
Y 2023-07-01 2024-09-30
Y 2022-07-01 2023-06-30
Y 2021-07-01 2022-06-30
X 2020-07-01 2021-06-30

Publisher: Khyber Medical College, Peshawar

Country: Pakistan

Year: 2020

Volume: 15

Issue: 4

Language: English

Categories

Abstract

The synthesis of surfactant fatty alkanolamide i.e. coco mono-ethanolamide was observed in this study. The fatty acid methyl ester (FAME) resulted from trans-esterification of coconut oil, treated with mono-ethanolamine to be coco mono-ethanolamide, using ZrCl4 as a catalyst and tert-amyl alcohol as a solvent. The observed reaction variables are the solvent ratio and stirring speed, and their effect on the converted FAME. The results showed that the 4:1 (v/w FAME) solvent ratio, and 300 rpm stirring speed gave the best results. Structural tests performed with FT-IR spectroscopy show that the surfactant obtained includes the fatty alkanolamide group. The results of this study are expected to produce cheap fatty alkanolamide surfactants obtained from renewable raw materials.


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