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Title: Tetracyclic Heteroaromatic Systems-Synthesis of Ethoxycarbonylphenylpyrido[3',2':5,6] Thiopyranoquinolines
Authors: Muhammad Naeem Khan, Misbahul Ain Khan, Noreen Aslam, Pir Bakhsh Khan, Ehsan ul Haq
Journal: Pakistan Journal of Scientific and Industrial Research (Series A: Physical Sciences)
Publisher: Pakistan Council of Scientific and Industrial Research
Country: Pakistan
Year: 2021
Volume: 64
Issue: 3
Language: en
DOI: 10.52763/PJSIR.PHYS.SCI.64.3.2021.191.194
Keywords: thiopyranoquinolinessynthesis of ethoxycarbonylSchiff's bases
7-benzylideneamino-5H-thiochromeno[2,3-b]pyridin-5-ones and 9-benzylideneamino-5H-thio- chromeno[2,3-b]pyridin-5-ones, on reaction with ethyl pyruvate to afford 1-ethoxycarbonyl-3-phenyl-12H- pyrido[3',2':5,6]thiopyrano[3,2-f]quinoline-12-ones and 4-ethoxycarbonyl-2-phenyl-7H- pyrido[3',2':5,6]thiopyrano[3,2-h]quinoline-7-ones respectively by the two different methods. These products were precipitated by addition of ethanol, water (1:1), were purified by recrystalizing from appropriate solvents and were characterized from their IR, 1H-NMR, mass spectra and elemental analysis data.
 
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