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Title: Room Temperature Selective Epoxidation of Cyclooctene Over Ag nanoparticles Supported on Tungsten Oxide with H2O2
Authors: Shilpi Ghosh, Shankha Shubhra Acharyya, Deependra Tripathi, Rajaram Bal
Journal: Journal of advanced catalysis science and technology
Publisher: Cosmos Scholars Publishing House
Year: 2014
Volume: 1
Issue: 1
Language: en
Keywords: H2O2Ag nanoparticlesTungsten (VI) oxideCycloocteneCyclooctene oxideSelective epoxidation.
We have prepared silver nanoparticles (AgNPs) supported on tungsten oxide (WO3) in presence of cetyltrimethyl ammonium bromide (CTAB), a catinic surfactant. The catalyst was characterized by XRD, ICP-AES, FT-IR, SEM and TEM. The catalyst was highly active for selective oxidation of cyclooctene to cyclooctene oxide at room temperature with H2O2. The reusability of the catalyst which is a prerequisite for practical applications was performed and it was found that the catalyst exhibits no significant changes in its catalytic activity even after three reuses. A cyclooctene conversion of 55% with cyclooctene oxide selectivity of ~99% was achieved over this catalyst
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