DefinePK

Abstract

A term symbol is used to describe atomic microstate states, which give the multiplicity and total angular momentum of the atomic state. Russel Sauder coupling scheme is used to generate terms of equivalent and non-equivalent electronic configurations. For equivalent electrons, the terms are calculated using Pauli’s principle, and the number of terms is limited and is calculated by the combination rule. The total possible electrons and total available electrons are used in the combination formula. In case of non-equivalent electrons, the number of terms are found by the permutation rule. The number of terms for equivalent electrons is less than the terms for non-equivalent electrons. The number of possible microstates for p2 and d5  configurations are 15 and 252 respectively. While the number of final microstates for 1p2p and 3d4d configurations are 36 and 100.  In the proposed study, a Python programme was developed that generates the microstate according to filled and half-filled subshell electronic configurations for equivalent, non-equivalent, and combinations of both. Examples of microstates for non-equivalent electrons of configuration 1s2s, sp, sd, ss, 2p3p, pd, pf, 3d4d, df, 4f5f and for equivalent electrons of configuration su, pv, dx, and f y are presented.